The big thing I see (sorry, pun intended) is that the SIONYX is a low light camera, where the FLIR is a thermal camera. Those are just different parts of the light spectrum, but they also show you different things. Some of the high end FLIR cameras include both low light and thermal imagers, and combine the two.
So then the question becomes which is better for boating, low light or thermal imaging, and I really don't know. Both let you "see" at night, and that's helpful no matter what. A low light image looks more like a daylight image, so can be less disorienting vs a thermal image. But a thermal image shows things that a low light image never will. Things like the contrast between a person in the water and the surrounding water. Or ice in the water. Both of those things really stand out. And only thermal will show you an overheating connection in an electric panel, or help you find heating hoses behind inaccessible panels. And you can get the FLIR in an exterior housing with point and tilt control, and gimbaled stabilization. But it costs... quite a bit.